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The Calibration module is most useful for analytical laboratories and metrological departments. It contains linear and nonlinear calibration models. Automatic detection of departures from linearity can be requested. Due to the fact that the module implements weighted regression, it can be successfully used for models with heteroscedastic errors. This feature can be useful namely for analyzing low-level measurement data (e.g. trace analysis).

PDF Calibration - Pdf manual

Calibration data example:
X Y Sample Repl1 Repl2 Repl3
1.281 25.53 No.1 33.69 33.74 33.73
1.281 25.58 No.2 39.25 39.25 39.27
2.558 51.37 No.3 50.6    
2.558 51.23 No.4 57.3    
5.430 106.4        
5.430 108.7        
7.373 148.4        
7.373 146.6        
11.59 233        

Input panel
Calibration

Different methods to determine detection limit
Calibration

Interactive calibration plot with zoom feature
Calibration

InteractiveCalibration calculator
Calibration

Other diagnostic plots
Calibration

Sample Text output:
Calibration        
         
Task name : Sheet36      
         
Data size: 17      
Significance level : 0.05      
Choice of calibration model : Automatic      
Used calibration model : Linear      
Suitability of the model : Model is correct      
Weighted regression used : Yes      
         
Parameters of calibration model        
Parameter Estimate St. deviation C.I. Lower C.I. Upper
Abs. 0.035973483 0.018686223 -0.003855259 0.075802226
X 1.000345445 0.006698099 0.986068785 1.014622106
         
Absolute term significance        
Value C.I. Lower C.I. Upper Conclusion  
0.035973483 -0.003855259 0.075802226 Insignificant  
         
Validation of slope        
Value C.I. Lower C.I. Upper Slope=1  
1.000345445 0.986068785 1.014622106 Yes  
         
Sensitivity of the model : 1.000345445      
         
Chosen factor K : 3      
Computed Blank signal std. deviation : 0.104747028      
         
Analysis of residuals        
Residual sum of squares : 0.164579099      
Average absolute residual : 0.069216963      
Correlation coefficient : 0.999523393      
Index Measured X Measured Y Computed Y Weight
1 0.31 0.38 0.351042915 12.24674589
2 1.31 1.30 1.343511625 11.9160705
3 1.56 1.58 1.59556717 11.70231418
4 1.56 1.58 1.59556717 11.70231418
5 2.52 2.53 2.556528936 9.915347572
6 2.65 2.72 2.682556709 9.536528779
7 2.66 2.72 2.69831018 9.486749624
8 4.39 4.44 4.431192054 3.194978968
9 4.54 4.61 4.572973298 2.83820524
10 4.58 4.66 4.620233713 2.728207814
11 7.64 7.73 7.6764072 0.527537807
12 7.64 7.73 7.6764072 0.527537807
13 7.65 7.59 7.692160671 0.52572007
14 7.70 7.97 7.739421086 0.520396645
15 9.86 9.79 9.897646693 0.388805078
16 9.86 9.79 9.897646693 0.388805078
17 9.81 9.60 9.850386278 0.390380962

One of the methods to estimate detection limits
Calibration
 
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